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B60002

Sigma-Aldrich

[(1R)-(endo,anti)]-(+)-3-Bromocamphor-8-sulfonic acid ammonium salt

99%

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About This Item

Empirical Formula (Hill Notation):
C10H15BrO4S · NH3
CAS Number:
14575-84-9
Molecular Weight:
328.22
EC Number:
238-616-9
MDL number:
MFCD00167438
UNSPSC Code:
12352115
PubChem Substance ID:
24891887
NACRES:
NA.22

Assay

99%

form

powder

optical activity

[α]25/D +84.5°, c = 4 in H2O

mp

284 °C (dec.) (lit.)

SMILES string

N.C[C@@]1(CS(O)(=O)=O)[C@@H]2CC[C@@]1(C)C(=O)[C@H]2Br

InChI

1S/C10H15BrO4S.H3N/c1-9-4-3-6(7(11)8(9)12)10(9,2)5-16(13,14)15;/h6-7H,3-5H2,1-2H3,(H,13,14,15);1H3/t6-,7+,9+,10-;/m1./s1

InChI key

GFBVBBRNPGPROZ-ZEMXJPTRSA-N

Application

[(1R)-(endo,anti)]-(+)-3-Bromocamphor-8-sulfonic acid ammonium salt can be used as a chiral resolving reagent in the resolution of piperidine intermediate, which is used in the synthesis of ORL-1 antagonist named J-113397.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A new synthesis of the ORL-1 antagonist 1-[(3R, 4R)-1-cyclooctylmethyl-3-hydroxymethyl-4-piperidinyl]-3-ethyl-1, 3-dihydro-2H-benzimidazol-2-one (J-113397) and activity in a calcium mobilization assay
Smith ED, et al.
Bioorganic & Medicinal Chemistry, 16(2), 822-829 (2008)

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