923486

(CyMPhos)PdCl₂

complex with CH₂Cl₂

• Synonym(s): 1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene palladium dichloride
• Empirical Formula (Hill Notation): C₄₂H₆₀Cl₂FeP₂Pd
• CAS Number: 2768152-20-9
• Molecular Weight: 860.04
• MDL number: MFCD01673219
• UNSPSC Code: 12352101
• NACRES: NA.21

Properties

• Quality Level: 100
• form: powder
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• greener alternative category: Aligned

Description

General description

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Application

(CyMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (CyMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Safety Information

• Pictograms: GHS08,GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H351
• Precautionary Statements: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable