704091
Tributyltin hydride solution
1 M in cyclohexane
Synonym(s):
Tributylstannane, Tributylstannyl hydride
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About This Item
Empirical Formula (Hill Notation):
C12H28Sn
CAS Number:
Molecular Weight:
291.06
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
form
liquid
reaction suitability
reagent type: reductant
concentration
1 M in cyclohexane
refractive index
n20/D 1.438
density
0.895 g/mL at 25 °C
SMILES string
CCCC[SnH](CCCC)CCCC
InChI
1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;
InChI key
DBGVGMSCBYYSLD-UHFFFAOYSA-N
Application
Reactant or reagent for:
- Alkyne hydrostannations
- Intramolcular cyclization for the synthesis of zoanthamine alkaloids
- Stereoselective C-glycosylation of pyranosides using Heck allylation
- Synthesis of phenylbutenoid dimers for use in treating diseases
- Preparation of N-acyl derivatives of ecteinascidin 770
- Syntehsis of cyclonucleosides using black light induced radical cyclization
Flash Point(F)
5.0 °F
Flash Point(C)
-15 °C
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Cassander P Titley-O'Neal et al.
The Science of the total environment, 449, 52-62 (2013-02-16)
Queen conch (Strombus gigas) are listed in CITES Appendix II. Populations may be declining due to anthropogenic inputs that include pollutants from boating activity. In the British Virgin Islands (BVI), some conch exhibit imposex, a condition in which male external
Shanshan Zhu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922, 21-26 (2013-02-19)
Analysis of tributyltin chloride (TBT) in environmental samples, such as seawater, is important in order to evaluate the TBT contamination and accumulation in the trophic chain. The environmental impact of organotin compounds has been a particular focus of analytical studies.
Detection, monitoring, and control of tributyltin--an almost complete success story.
Peter Matthiessen
Environmental toxicology and chemistry, 32(3), 487-489 (2013-02-19)
Raquel Chamorro-García et al.
Environmental health perspectives, 121(3), 359-366 (2013-01-17)
We have previously shown that exposure to tributyltin (TBT) modulates critical steps of adipogenesis through RXR/PPARγ and that prenatal TBT exposure predisposes multipotent mesenchymal stem cells (MSCs) to become adipocytes by epigenetic imprinting into the memory of the MSC compartment.
P Iyapparaj et al.
Ecotoxicology and environmental safety, 89, 231-238 (2013-01-09)
The present study evaluated reproductive toxicity and antifouling activity of methanolic extract of seagrass Syringodium isoetifolium (25 μg/ml) relative to the conventional antifoulant, tributyltin (TBT; 100 ng/l) on the ovarian development of the brown mussel Perna indica. Gonado Somatic Index
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