Reagent/catalyst for various organic transformations, e.g. allylation of aldehydes, ketones, and quinones; Diels-Alder reaction; the aldol reaction; Michael additions; the reductive Friedel-Crafts;
Chemistry (Weinheim an der Bergstrasse, Germany), 6(19), 3491-3494 (2000-11-10)
Group 3-15 metal chlorides (Lewis acids) were classified on the basis of activity and aldehyde- and aldimine-selectivity in an addition reaction of a silyl enol ether. Based on the experimental results, metal chlorides (Lewis acids) were classified as follows: A
Chapman, C. J.; Frost, C. G. et al.
Tetrahedron Letters, 42, 773-773 (2001)
Loh, T.-P.; Li, X.-R.,
Angewandte Chemie (International Edition in English), 36, 980-980 (1997)
Chemistry (Weinheim an der Bergstrasse, Germany), 19(3), 828-833 (2012-12-21)
Magnesium, indium, palladium: An efficient one-pot procedure for the direct preparation of triorganoindium reagents from organic halides by means of magnesium insertion in the presence of InCl(3) and LiCl is reported (see scheme). The organoindium reagents are obtained in good
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