538086
3-Mercaptopropyl-functionalized silica gel
200-400 mesh, extent of labeling: 1.2 mmol/g loading
Synonym(s):
Mercapto-3 functionalized silica gel
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About This Item
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reaction suitability
reagent type: catalyst
reagent type: chelator
extent of labeling
1.2 mmol/g loading
surface area
500 m2/g
particle size
200-400 mesh
pore size
60 Å pore size
SMILES string
O=[SiH2].CCCS
InChI key
XVEMJYXZUPRUMO-UHFFFAOYSA-N
Application
3-Mercaptopropyl-functionalized silica gel (MPS) is a resin which can be used:
- As a binding agent in diffusive gradients in thin film (DGT) technique for the determination of labile Hg[1], methylmercury[2] and arsenic (AsIII) concentrations.[3]
- As a heterogeneous support for immobilizing titanocene catalysts for hydrosilylation of 2-phenylpyrroline.[4]
- As a reducing agent for sulfoxide deoxygenation.[5]
- As a metal scavenger for various metals such as Pd, Pt, Cu, Ag and Pb.[6]
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Measurements of dissolved methylmercury in natural waters using diffusive gradients in thin film (DGT)
Clarisse O and Hintelmann H
Journal of Environmental Monitoring, 8(12), 1242-1247 (2006)
Strong evidence of solution-phase catalysis associated with palladium leaching from immobilized thiols during Heck and Suzuki coupling of aryl iodides, bromides, and chlorides
Richardson JM and Jones CW
J. Catal., 251(1), 80-93 (2007)
Speciation of dissolved inorganic arsenic by diffusive gradients in thin films: selective binding of AsIII by 3-mercaptopropyl-functionalized silica gel
Bennett WW, et al.
Analytical Chemistry, 83(21), 8293-8299 (2011)
Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines
Gruber-Woelfler H, et al.
Dalton Transactions, 41(41), 12711-12719 (2012)
Cathleen M Crudden et al.
Journal of the American Chemical Society, 127(28), 10045-10050 (2005-07-14)
The functionalization of SBA-15 with mercaptopropyl trimethoxysilane leads to a material capable of absorbing Pd from organic and aqueous solutions. The resulting Pd-loaded material acts as a catalyst for the Suzuki-Miyaura and Mizoroki-Heck coupling reactions. Leaching studies show that the
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