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510068

Sigma-Aldrich

Raney®-Nickel

W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst

Synonym(s):

Nickel sponge

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About This Item

Linear Formula:
AlNi
CAS Number:
7440-02-0
MDL number:
MFCD00167392
UNSPSC Code:
12161600
PubChem Substance ID:
24873472
NACRES:
NA.22

form

slurry

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 3202

concentration

in H2O

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Application

Useful as a selective reducing agent for hydrogenation of organic compounds

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Signal Word

Danger

Hazard Statements

H250,H317,H351,H372

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)
Toth, M.; Somsak, L.,
Tetrahedron Letters, 42, 2723-2723 (2001)
Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Fariborz Amini et al.
International journal of orthodontics (Milwaukee, Wis.), 24(1), 43-44 (2013-06-05)
In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a
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Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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