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50971

Sigma-Aldrich

Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide

≥95.0%

Synonym(s):

Tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl)amide

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About This Item

Linear Formula:
[CH3(CH2)5]3P[N(SO2CF3)2](CH2)13CH3
CAS Number:
460092-03-9
Molecular Weight:
764.00
MDL number:
MFCD04117695
UNSPSC Code:
12352100
PubChem Substance ID:
57651289
NACRES:
NA.22

Assay

≥95.0%

impurities

≤1.0 water (Karl Fischer)

density

1.07 g/mL at 20 °C (lit.)

SMILES string

FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C32H68P.C2F6NO4S2/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h5-32H2,1-4H3;/q+1;-1

InChI key

HYNYWFRJHNNLJA-UHFFFAOYSA-N

Related Categories

General description

Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide [P6,6,6,14][Ntf2] is an ionic liquid generally used in biosensors electrodeposition, and synthetic chemistry applications.

Application

[P6,6,6,14][Ntf2] can be used in:
  • The electrodeposition of nano and microcrystalline metals for electrochemical applications.
  • The synthesis of amino acid ionic liquid functionalized graphene (AAIL-GR) applicable as a biosensor.
  • The investigation of interactions between ionic liquids and fluorinated alkanes.
  • The synthesis of pure rutile and anatase phases of nanocrystalline TiO2.

Other Notes

Ionic liquid for copolymerisation

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

125.6 °F

Flash Point(C)

52 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis and Characterization of Rutile and Anatase in Air-and Water-Stable Ionic Liquids with and without Isopropanol as a Cosolvent.
Al Zoubi M, et al.
Australian Journal of Chemistry, 61(9), 704-711 (2008)
Electrochemical biosensing platform based on amino acid ionic liquid functionalized graphene for ultrasensitive biosensing applications
Lu X, at al.
Biosensors And Bioelectronics, 62(39), 134-139 (2014)
Xianbo Lu et al.
Biosensors & bioelectronics, 62, 134-139 (2014-07-06)
In this study, a facile non-covalent method was developed for preparing water-soluble graphene with excellent electronic conductivity. Room temperature ionic liquids (ILs) with high ionic conductivity were used for the non-covalent surface functionalization of graphene through π-π stacking interactions. Compared
Interactions of fluorinated gases with ionic liquids: Solubility of CF4, C2F6, and C3F8 in trihexyltetradecylphosphonium bis (trifluoromethylsulfonyl) amide.
Pison L, et al.
The Journal of Physical Chemistry B, 112(39), 12394-12400 (2008)
Nathalie M Rocher et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(14), 3435-3447 (2009-01-10)
Electrodeposition of aluminium is possible from solutions of AlCl(3) dissolved in the 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (C(4)mpyrNTf(2)) ionic liquid. However, electrodeposition is dependant on the AlCl(3) concentration as it only occurs at concentrations >1.6 mol L(-1). At these relatively high AlCl(3) concentrations
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