424889

Rhodium(II) heptafluorobutyrate dimer

97%

• Synonym(s): Dirhodium heptafluorobutyrate dimer, Dirhodium tetrakis(perfluorobutyrate), Tetrakis(perfluorobutyrato)dirhodium
• Linear Formula: [(CF₃CF₂CF₂CO₂)₂Rh]₂
• CAS Number: 73755-28-9
• Molecular Weight: 1057.93
• MDL number: MFCD00799582
• UNSPSC Code: 12352302
• PubChem Substance ID: 24866595
• NACRES: NA.23

Properties

• Assay: 97%
• form: powder
• reaction suitability: reagent type: catalyst; core: rhodium
• mp: >300 °C (lit.)
• SMILES string: FC(F)(F)C(F)(F)C(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)C(F)(F)C(F)(F)F.FC(F)(F)C(F)(F)C(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)C(F)(F)C(F)(F)F
• InChI: 1S/4C4HF7O2.2Rh/c4*5-2(6,1(12)13)3(7,8)4(9,10)11;;/h4*(H,12,13);;/q;;;;2*+2/p-4
• InChI key: BNCXPORMMOBRMR-UHFFFAOYSA-J

Description

Application

Recently used in the catalytic preparation of macrocycles and in the efficient synthesis of chiral β-substituted (E)-crotylsilanes.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves