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379875

Sigma-Aldrich

Palladium(II) acetate

99.98% trace metals basis

Synonym(s):

Pd(OAc)2, [Pd(OAc)2]3

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1 G
MXP 4,167.00
5 G
MXP 16,413.00

MXP 4,167.00


Estimated to ship onMarch 21, 2025


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1 G
MXP 4,167.00
5 G
MXP 16,413.00

About This Item

Linear Formula:
Pd(OCOCH3)2
CAS Number:
Molecular Weight:
224.51
Beilstein:
6086766
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

MXP 4,167.00


Estimated to ship onMarch 21, 2025


Request a Bulk Order

Quality Level

Assay

99.98% trace metals basis

form

powder

reaction suitability

core: aluminum
reagent type: catalyst

mp

216.3-223.7 °C (dec.)

SMILES string

CC(O[Pd]OC(C)=O)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

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Application

A non-halogenated palladium(II) complex. It has been used as a catalyst for coupling reactions[1] and as a precursor to prepare palladium-containing materials for heterogeneous catalysis.[2][3]

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Jujjuri, S.; et al.
J. Catal., 239 (2), 486-500 (2006)
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 53(44), 11895-11899 (2014-09-11)
A palladium-catalyzed dehydrogenative coupling between diarylamines and olefins has been discovered for the synthesis of substituted indoles. This intermolecular annulation approach incorporates readily available olefins for the first time and obviates the need of any additional directing group. An ortho palladation
Xu, J.; et al.
Journal of Nanoparticle Research, 7 (4-5), 449-467 (2005)
Palladium-catalyzed synthesis of benzofurans and coumarins from phenols and olefins.
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 52(48), 12669-12673 (2013-10-16)
Hu Kang et al.
Journal of the American Chemical Society, 128(18), 6194-6205 (2006-05-04)
A novel type of "X-shaped" two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH(2)Cl(2)) while maintaining a very large first hyperpolarizability (beta).

Questions

1–4 of 4 Questions  
  1. What is the solubility of Product 379875, Palladium (II) acetate?

    1 answer
    1. It is soluble in chloroform and acetone.  It will decompose in hydrochloric acid.  It is insoluble in water.

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  2. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  3. What is the melting point of Product 379875, Palladium (II) acetate?

    1 answer
    1. The melting point of this product is approximately 680 deg C.

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  4. Is Product 379875, Palladium (II) acetate, really 99.98% pure?

    1 answer
    1. The purity of 99.98% is not the actual chemical purity, but rather the purity based on trace metal content.  A maximum of 300ppm total metallic impurities would be allowed.

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