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72252

Sigma-Aldrich

Nickel(II) nitrate hexahydrate

puriss. p.a., ≥98.5% (KT)

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About This Item

Linear Formula:
Ni(NO3)2 · 6H2O
CAS Number:
13478-00-7
Molecular Weight:
290.79
EC Number:
236-068-5
MDL number:
MFCD00149805
UNSPSC Code:
12352302
PubChem Substance ID:
329763935
NACRES:
NA.21
Assay:
≥98.5% (KT)
form:
crystals or chunks

grade

puriss. p.a.

Quality Level

200

Assay

≥98.5% (KT)

form

crystals or chunks

mp

56 °C (lit.)

density

2.05 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤10 mg/kg
Co: ≤100 mg/kg
Cu: ≤20 mg/kg
Fe: ≤10 mg/kg
K: ≤50 mg/kg
Na: ≤50 mg/kg
Pb: ≤10 mg/kg
Zn: ≤10 mg/kg

SMILES string

O.O.O.O.O.O.[Ni++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;;

InChI key

AOPCKOPZYFFEDA-UHFFFAOYSA-N

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General description

Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.

Application

Nickel(II) nitrate hexahydrate may be used as precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders and Ni(II) oxide aerogels.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL2738
BCCJ2778
BCCH0292
BCCF3726
BCCF3725

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Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2?6H2O, in comparison to Co(NO3)2?6H2O and Ca(NO3)2?4H2O.
Brockner W, et al.
Thermochimica Acta, 456(1), 64-68 (2007)
Monolithic nickel (II)-based aerogels using an organic epoxide: the importance of the counterion.
Gash AE, et al.
Journal of Non-Crystalline Solids, 350, 145-151 (2004)
Synthesis and structural characterization of layered Li[Ni1/3Co1/3Mn1/3]O2 cathode materials by ultrasonic spray pyrolysis method.
Park SH, et al.
Electrochimica Acta, 49(4), 557-563 (2004)
Natalie Baho et al.
Inorganic chemistry, 46(1), 299-308 (2007-01-03)
The complexes [(dpdpm)Ni(2-NO3)2] (1), [(dpdpm)Ni(2-NO3)(1-NO3)(CH3CN)] (2), [(dpdpm)2Ni(1-NO3)(H2O)]NO3 (3), and [(dpdpm)2Ni(H2O)2][NO3]2 (4) (dpdpm = diphenyl(dipyrazolyl)methane, Ph2C(C3N2H3)2), have been prepared and characterized by IR and UV-vis-NIR spectroscopy and X-ray diffraction studies. X-ray studies have confirmed that complexes 1-4 all adopt variously distorted
B Vikhoff et al.
Acta radiologica (Stockholm, Sweden : 1987), 36(3), 323-325 (1995-05-01)
An investigation regarding possible artefacts from dental filling materials in MR imaging is presented including 9 types of such materials from various manufacturers. Freshly extracted teeth were prepared and the filling materials were handled according to manufacturers' instructions. The teeth
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