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Carmoisine

analytical standard

Synonym(s):

Chromotrope FB, Azorubine, Food red 3, Acid Red 14, Disodium 4-hydroxy-3-[(4-sulfo-1-naphthalenyl)azo]-1-naphthalenesulfonate, Mordant Blue 79

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About This Item

Empirical Formula (Hill Notation):
C20H12N2Na2O7S2
CAS Number:
Molecular Weight:
502.43
Colour Index Number:
14720
EC Number:
MDL number:
UNSPSC Code:
12164500
PubChem Substance ID:
E Number:
E122
NACRES:
NA.24

grade

analytical standard

Quality Level

Assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

neat

SMILES string

[Na+].[Na+].Oc1c(cc(c2ccccc12)S([O-])(=O)=O)\N=N\c3ccc(c4ccccc34)S([O-])(=O)=O

InChI

1S/C20H14N2O7S2.2Na/c23-20-15-8-4-3-7-14(15)19(31(27,28)29)11-17(20)22-21-16-9-10-18(30(24,25)26)13-6-2-1-5-12(13)16;;/h1-11,23H,(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2/b22-21+;;

InChI key

YSVBPNGJESBVRM-ZPZFBZIMSA-L

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General description

Carmoisine is a synthetic azo dye, commonly added to food, beverages, medicine, and cosmetics. It is frequently used alone or in combination with Allura red (E 129) and Ponceau 4R synthetic dyes. It is reported to be used for purposes where the food needs to be heat-treated post-fermentation.

Application

Carmoisine may be used as an analytical reference standard for the quantification of the analyte in the following:
  • Food samples using spectrophotometric analysis technique.
  • Sweets and beverages using differential pulse polarography.
  • Synthetic mixtures and beverages using high performance liquid chromatography with diode array detection (HPLC-DAD).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

>437.0 °F

Flash Point(C)

> 225 °C


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Determination of Carmoisine, Allura red and Ponceau 4R in sweets and soft drinks by Differential Pulse Polarography
Chanlon S, et al.
J. Food Compos. Anal., 18(6), 503-515 (2005)
Spectrophotometric determination of carmoisine after cloud point extraction using Triton X-114
Karatepe A, et al.
Turkish Journal of Chemistry, 41(2), 256-262 (2017)
Four derivative spectrophotometric methods for the simultaneous determination of carmoisine and ponceau 4R in drinks and comparison with high performance liquid chromatography
Turak F, et al.
International Journal of Analytical Chemistry, 2014 (2014)
C Gibb et al.
Biochemical pharmacology, 36(14), 2325-2330 (1987-07-15)
Several natural and synthetic food and drink constituents were tested in vitro for their inhibitory actions on phenolsulphotransferase P and M (PST P, PST M) and monoamine oxidase A and B (MAO A, MAO B). Cyanidin 3-rutinoside, a simple anthocyanin
Meenakshi Tripathi et al.
Journal of AOAC International, 87(3), 657-663 (2004-08-04)
A simple method has been developed for the extraction, separation, and determination of synthetic colors in ice cream samples. The process involves the breakdown of emulsion by neutral detergents (Triton X-100 and Tween 20) followed by extraction with petroleum ether

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