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247367

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphine

≥99%

Synonym(s):

meso-Tetraphenylporphyrin, TPP

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About This Item

Empirical Formula (Hill Notation):
C44H30N4
CAS Number:
Molecular Weight:
614.74
Beilstein:
379542
EC Number:
MDL number:
UNSPSC Code:
12171500
PubChem Substance ID:
NACRES:
NA.47

Quality Level

Assay

≥99%

form

crystalline powder

impurities

<0.1% corresponding chlorin

mp

>300 °C (lit.)

solubility

toluene: 0.03 g/L, clear

λmax

415 nm

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

c1ccc(cc1)-c2c3ccc(n3)c(-c4ccccc4)c5ccc([nH]5)c(-c6ccccc6)c7ccc(n7)c(-c8ccccc8)c9ccc2[nH]9

InChI

1S/C44H30N4/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36/h1-28,45,48H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

YNHJECZULSZAQK-LWQDQPMZSA-N

Gene Information

human ... TERT(7015)

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Mohammed Ibrahim et al.
Journal of the American Chemical Society, 128(51), 16834-16845 (2006-12-21)
Heme proteins bind the gaseous ligands XO (X = C, N, O) via backbonding from Fe d(pi) electrons. Backbonding is modulated by distal interactions of the bound ligand with the surrounding protein and by variations in the strength of the
C Ni et al.
Guang pu xue yu guang pu fen xi = Guang pu, 20(5), 749-750 (2003-08-30)
The electronic absorption spectra and thermodynamics of axial coordination reaction of 5-(4-valine butoxyphenyl)-10,15,20-tri(4-chlorophenyl)porphintozinc with pyrimidine in CHCl3 were studied. Coordination numbers and equilibrium constants of axial coordination reaction were measured by visible spectra techniques. The changes of standard molar enthalpies
Aruna Roby et al.
Cancer biology & therapy, 6(7), 1136-1142 (2007-07-06)
Poorly soluble photosensitizer, meso-tetraphenylporphine (TPP), was solubilized using the polymeric micelles prepared from polyethylene glycol-phosphatidyl ethanolamine conjugate (PEG-PE). TPP-loaded PEG-PE micelles have been additionally modified with tumor-specific monoclonal 2C5 antibody (mAb 2C5), which resulted in significantly improved anticancer effect of
Jun Xu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 75(5), 1381-1387 (2010-02-23)
Resonance Raman spectra of free-base tetraphenylporphine (TPP) were obtained with 397.9, 416, and 435.7nm excitation wavelengths and density functional calculations were done to elucidate the electronic transitions and the resonance Raman spectra (RRs) of TPP. The RRs indicate that the
A V Udal'tsov et al.
Biophysical chemistry, 83(2), 141-152 (2000-02-15)
Properties of protonated dimeric forms of meso-tetraphenylporphine (TPP) and meso-tetra(p-aminophenyl)porphine (TAPP) bound with copolymer and also complexes produced by associated TAPP bound with copolymer, Mn2+, and Fe3+ are investigated by absorption, luminescence, and Raman spectroscopy. According to absorption spectra of

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