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ALD00612

(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide

≥95%

Synonym(s):

Yu MPAAM ligand

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About This Item

Empirical Formula (Hill Notation):
C13H20N2O
CAS Number:
2226371-98-6
Molecular Weight:
220.31
MDL number:
MFCD31977865
UNSPSC Code:
12352200
NACRES:
NA.22

Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

storage temp.

−20°C

SMILES string

N([C@H](CN(C)C)Cc1ccccc1)C(=O)C

InChI

1S/C13H20N2O/c1-11(16)14-13(10-15(2)3)9-12-7-5-4-6-8-12/h4-8,13H,9-10H2,1-3H3,(H,14,16)/t13-/m0/s1

InChI key

PXPSPBKAWKBCMJ-ZDUSSCGKSA-N

Related Categories

Application

(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide is an MPAAM ligand developed in the Yu Group for the Pd-catalyzed enantioselective C(sp3)-H arylation of fre cyclopropanecarboxylic and aminoisobutyric acids.

Other Notes

Pd(II)-Catalyzed Enantioselective C(sp3)-H Arylation of Free Carboxylic Acids

related product

Product No.
Description
Pricing

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Peng-Xiang Shen et al.
Journal of the American Chemical Society, 140(21), 6545-6549 (2018-05-10)
A monoprotected aminoethyl amine chiral ligand based on an ethylenediamine backbone was developed to achieve Pd-catalyzed enantioselective C(sp3)-H arylation of cyclopropanecarboxylic and 2-aminoisobutyric acids without using exogenous directing groups. This new chiral catalyst affords new disconnection for preparing diverse chiral

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