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288225

Sigma-Aldrich

Chloro(triethylphosphine)gold(I)

97%

Synonym(s):

(Triethylphosphine)gold(I) chloride

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About This Item

Linear Formula:
(C2H5)3PAuCl
CAS Number:
15529-90-5
Molecular Weight:
350.58
EC Number:
239-572-3
MDL number:
MFCD00013205
UNSPSC Code:
12161600
PubChem Substance ID:
24857327
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: gold
reagent type: catalyst

bp

210 °C/0.03 mmHg (lit.)

mp

84-86 °C (lit.)

SMILES string

Cl[Au].CCP(CC)CC

InChI

1S/C6H15P.Au.ClH/c1-4-7(5-2)6-3;;/h4-6H2,1-3H3;;1H/q;+1;/p-1

InChI key

SYBBXLKWGHAVHP-UHFFFAOYSA-M

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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P Davis et al.
Arthritis and rheumatism, 26(1), 82-86 (1983-01-01)
The effect of sodium aurothiomalate and triethylphosphine gold on the generation of superoxide radicals by chemotactic tripeptide-activated polymorphonuclear leukocytes has been investigated using a cytochrome C reduction technique. Neither gold compound inhibited the binding of the tripeptide to cells. Sodium
S K Mallya et al.
Biochemical and biophysical research communications, 144(1), 101-108 (1987-04-14)
Six gold(I) salts, some of which are used as drugs in chrysotherapy, are shown to be inhibitors of two forms of human neutrophil collagenase. The IC50 values vary over six orders of magnitude, the lowest being 3.5 nM for Myocrisin.
R M Snyder et al.
Molecular pharmacology, 32(3), 437-442 (1987-09-01)
Auranofin (AF) is an orally active chrysotherapeutic agent used for the treatment of rheumatoid arthritis, a self-perpetuating inflammatory disease. Because of reports suggesting that AF and other gold complexes can, under certain circumstances, exacerbate rheumatoid inflammatory lesions in humans and
N A Malik et al.
Journal of inorganic biochemistry, 12(4), 317-322 (1980-07-01)
Contrasting reactions of the antiarthritic complexes ClAuPEt3 and ClAu(PEt3)2 with blood have been studied by 31P nmr spectroscopy. The monophosphine complex has two binding sites in erythrocytes, probably at the SH groups of glutathione and haemoglobin. The bis complex solidifies
Cellular and molecular pharmacology of auranofin and related gold complexes.
S T Crooke et al.
Biochemical pharmacology, 35(20), 3423-3431 (1986-10-15)
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