221171

Pinacol

98%

• Synonym(s): 2,3-Dimethyl-2,3-butanediol, Tetramethylethylene glycol
• Linear Formula: HOC(CH₃)₂C(CH₃)₂OH
• CAS Number: 76-09-5
• Molecular Weight: 118.17
• Beilstein: 1340501
• EC Number: 200-933-5
• MDL number: MFCD00004462
• UNSPSC Code: 12352100
• PubChem Substance ID: 24853219
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: 98%
• form: solid
• bp: 171-172 °C/739 mmHg (lit.)
• mp: 40-43 °C (lit.)
• solubility: alcohol: freely soluble; diethyl ether: freely soluble; hot water: freely soluble
• functional group: hydroxyl
• SMILES string: CC(C)(O)C(C)(C)O
• InChI: 1S/C6H14O2/c1-5(2,7)6(3,4)8/h7-8H,1-4H3
• InChI key: IVDFJHOHABJVEH-UHFFFAOYSA-N

Description

General description

The pinacol coupling reaction with the inorganic electride [Ca₂N](+)·e(−) as an electron donor in organic solvents was studied.

Application

Pinacol is a 1,2-diol that can be used:

• As a ligand to prepare uranyl complexes by reacting with uranyl nitrate and acetate hydrates.
• To prepare pinacolone and 2,3-dimethyl-1,3-butadiene by typical pinacol rearrangement reaction.
• As a reactant to synthesize 4-(4,4,5,5-tetramethyl-1,3,2-bioxaborolan-2-yl)benzoic acid, which is used to prepare derivatives of 4-acetoxy-3-phenylbenzaldehyde.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): 170.6 °F - closed cup
• Flash Point(C): 77 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves