679453
2-(Bromomethyl)phenylboronic acid
Synonym(s):
α-Bromo-o-tolueneboronic acid, o-Boronobenzyl bromide
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About This Item
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mp
158-162 °C
Quality Level
functional group
bromo
storage temp.
2-8°C
SMILES string
OB(O)c1ccccc1CBr
InChI
1S/C7H8BBrO2/c9-5-6-3-1-2-4-7(6)8(10)11/h1-4,10-11H,5H2
InChI key
MYVJCOQGXCONPE-UHFFFAOYSA-N
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General description
May contain varying amounts of anhydride.
Application
2-(Bromomethyl)phenylboronic acid can be used as a reactant to synthesize:
- Boronic acid-functionalized benzyl viologen (o-BBV) from 4,4′-bipyridine. o-BBV finds its application as a chemosensor to sense glucose in aqueous water.
- 2-(azidomethyl)phenylboronic acid, which is further employed in the preparation of isoquinoline derivatives.
- Aryl boronic acid derivatives as fluorescent probe for hydrogen peroxide detection.
Reactant involved in:
- Studies of carbon-boron bond cleavage of phenylboronate-pendant cyclen
- Development of a sensory system to detect glucose or other monosaccharides and hydroxycarboxylates
- Synthesis of boronated triaryl and tetraaryl phosphonium salts used in cytotoxicity studies
- Colorimetry and fluorometry mercury determination with chemosensors composed of rhodamine and boronic acid groups
- Synthesis of imidazolium-containing boronic acids used as fluoride ion sensors
- Reactions with adenine for molecules with antiinflammatory antitumor activities
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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