559121

Ethyl (2-methoxybenzoyl)acetate

99%

• Synonym(s): 3-(2-Methoxyphenyl)-3-oxopropanoic acid ethyl ester, Ethyl (o-methoxybenzoyl)acetate, Ethyl 3-(2-methoxyphenyl)-3-oxopropanoate, Ethyl 3-(2-methoxyphenyl)-3-oxopropionate
• Linear Formula: CH₃OC₆H₄COCH₂CO₂CH₂H₃C
• CAS Number: 41607-95-8
• Molecular Weight: 222.24
• MDL number: MFCD01311633
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879798
• NACRES: NA.22

Properties

• Assay: 99%
• refractive index: n20/D 1.5320 (lit.)
• bp: 259-260 °C (lit.)
• density: 1.144 g/mL at 25 °C (lit.)
• functional group: ester; ketone
• SMILES string: CCOC(=O)CC(=O)c1ccccc1OC
• InChI: 1S/C12H14O4/c1-3-16-12(14)8-10(13)9-6-4-5-7-11(9)15-2/h4-7H,3,8H2,1-2H3
• InChI key: KROPYAVVJDXRPH-UHFFFAOYSA-N

Description

Application

Reactant for:

• Preparation of N-allyl/propargyl enamine carboxylates
• Enantioselective ruthenium-catalyzed hydrogenation
• Hydrosilylation reactions catalyzed by chiral BINAM N-heterocyclic carbene rhodium complex
• Preparation of potential herbicidal agents

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves