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449857

Sigma-Aldrich

Lanthanum(III) fluoride

anhydrous, powder, 99.99% trace metals basis

Synonym(s):

Lanthanum fluoride, Lanthanum trifluoride

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About This Item

Linear Formula:
LaF3
CAS Number:
13709-38-1
Molecular Weight:
195.90
EC Number:
237-252-8
MDL number:
MFCD00011073
UNSPSC Code:
12352302
PubChem Substance ID:
24868514
NACRES:
NA.23

grade

anhydrous

Quality Level

100

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: lanthanum

impurities

≤200.0 ppm Trace Rare Earth Analysis

density

5.936 g/mL at 25 °C (lit.)

SMILES string

F[La](F)F

InChI

1S/3FH.La/h3*1H;/q;;;+3/p-3

InChI key

BYMUNNMMXKDFEZ-UHFFFAOYSA-K

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Application

Employed extensively in the preparation and study of fluoride glasses.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Andy Y H Lo et al.
Journal of the American Chemical Society, 129(15), 4687-4700 (2007-03-28)
Multinuclear solid-state NMR spectroscopy and powder X-ray diffraction (XRD) experiments are applied to comprehensively characterize a series of pure and lanthanide-doped LaF3 nanoparticles (NPs) that are capped with di-n-octadectyldithiophosphate ligands (Ln3+ = diamagnetic Y3+ and Sc3+ and paramagnetic Yb3+ ions)
Jian-Xin Meng et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 66(1), 81-85 (2006-07-04)
LaF3:Eu3+ nanoparticles were prepared by a simple hydrothermal process at low temperature and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and fluorescence spectrum. Well-dispersed nanoparticles with an average size of 30 nm and a hexagonal shape were obtained.
Radiative lifetime modification of LaF₃:Nd nanoparticles embedded in 3D silicon photonic crystals.
Hailong Ning et al.
Advanced materials (Deerfield Beach, Fla.), 24(23), OP153-OP158 (2012-05-10)
Ibrahim H A Badr et al.
Journal of the American Chemical Society, 127(15), 5318-5319 (2005-04-14)
A highly selective, sensitive, and reversible fluoride optical sensing film based on aluminum(III)octaethylporphyrin as a fluoride ionophore and a lipophilic pH indicator as the optical transducer is described. The fluoride optical sensing films exhibit a submicromolar detection limit and high
Peter R Diamente et al.
Langmuir : the ACS journal of surfaces and colloids, 22(4), 1782-1788 (2006-02-08)
The binding of Eu3+-doped LaF3 nanoparticles with biotin moieties at the surface of the stabilizing ligand layer to avidin, immobilized on cross-linked aragose beads, is described. The biotin moieties were attached to the nanoparticles by reaction of an activated ester
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