163678
Thioacetamide
ACS reagent, ≥99.0%
Synonym(s):
TAA, Ethanethioamide
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About This Item
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grade
ACS reagent
Quality Level
Assay
≥99.0%
form
solid
mp
108-112 °C (lit.)
solubility
passes test 2%
functional group
amine
SMILES string
CC(N)=S
InChI
1S/C2H5NS/c1-2(3)4/h1H3,(H2,3,4)
InChI key
YUKQRDCYNOVPGJ-UHFFFAOYSA-N
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General description
Thioacetamide (TAA) is a thiocarbonyl compound commonly used as a corrosion inhibitor. It prevents corrosion by forming a protective layer on metal surfaces. It undergoes deuterium exchange reaction with D2O to afford N-dideuterated thioacetamide. Infrared spectral investigations of thioacetamide and its deuterated derivative (N-dideuterated thioacetamide) have been reported.
Application
Hepatotoxin and carcinogen. An additive in enantioselective reduction of β-keto esters with immobilized baker′s yeast.
It may also be used as a sulfide source to prepare metal sulfides of metal ions like cadmium, nickel, zinc and copper.
Thioacetamide has been used as a source of sulfur required for the synthesis of CdS nanoparticlesand quantum dots.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Cancer Research, 17, 954-954 (1952)
Synthesis of nickel sulfide powders by thioacetamide in the presence of urea.
Journal of the American Ceramic Society. American Ceramic Society, 80(4), 941-951 (1997)
Synthesis of copper sulfide nanowhisker via sonochemical way and its characterization
Chemistry Letters (Jpn), 32(2), 198-199 (2003)
Effect of molecular structure on the efficiency of amides and thiosemicarbazones used for corrosion inhibition of mild steel in hydrochloric acid
Materials Chemistry and Physics, 60, 79-90 (1999)
A new preparation of zinc sulfide nanoparticles by solid-state method at low temperature.
Materials Research Bulletin, 35(5), 695-701 (2000)
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