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Key Documents

C11006

Sigma-Aldrich

Carbohydrazide

98%

Synonym(s):

1,3-Diaminourea, Carbodihydrazide, Carbonohydrazide, N,N′-Diaminourea

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About This Item

Linear Formula:
CO(NHNH2)2
CAS Number:
Molecular Weight:
90.08
Beilstein:
1747069
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

crystals

mp

150-153 °C (lit.)

SMILES string

NNC(=O)NN

InChI

1S/CH6N4O/c2-4-1(6)5-3/h2-3H2,(H2,4,5,6)

InChI key

XEVRDFDBXJMZFG-UHFFFAOYSA-N

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Application

Carbohydrazide can be used:
  • As an oxygen scavenger.
  • In the synthesis of polydentate Schiff base ligands with various aldehydes and ligands by condensation.
  • In the synthesis of trifluoromethyl-containing (E)-N′-arylidene-1H-pyrazole-1-carbohydrazides by cyclocondensation reaction which shows antioxidant and antimicrobial properties.

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1

Supplementary Hazards

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Experimental investigation and optimization of carbohydrazide application using different alkalization agents on boilers All-Volatile treatment.
Vasile-Pafili SMV and Bartzis JG
Applied Thermal Engineering, 30(10), 1269-1275 (2010)
Huisheng Huang et al.
Journal of hazardous materials, 179(1-3), 21-27 (2010-04-07)
The molecular geometry, electronic structure, infrared spectra and thermochemical properties of cobalt and nickel tris(carbohydrazide) perchlorates (CoCP and NiCP) as well as copper bis(carbohydrazide) perchlorate (CuCP) were investigated using the Heyd-Scuseria-Ernzerhof (HSE) screened hybrid density functional. The results show that
New trifluoromethyl-containing (E)-N?-arylidene-[3-alkyl (aryl/heteroaryl)-4, 5-dihydro-1H-pyrazol-1-yl] carbohydrazides: Synthesis, crystal structure and antimicrobial/antioxidant activity.
Bonacorso HG, et al.
Journal of Fluorine Chemistry, 135(10), 303-314 (2012)
Mateusz Wierzbicki et al.
Nanoscale research letters, 14(1), 320-320 (2019-10-12)
Antibacterial surfaces coated with nanomaterials, including silver nanoparticles, are considered effective alternative antimicrobial agents that can be used instead of antibiotics and chemical agents. However, reports of the potential toxicity of these materials raise questions about the safety of their
Synthesis, structure and reactivity of zirconium (IV), vanadium (IV), cobalt (II), nickel (II) and copper (II) complexes derived from carbohydrazide schiff base ligands.
Warad, DU, et al.
Indian Journal of Chemistry, 39A(10), 415-420 (2000)

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