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928917

Sigma-Aldrich

[CF3]8-DPPF

≥95%

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About This Item

Empirical Formula (Hill Notation):
C42H20F24FeP2
CAS Number:
70236-68-9
Molecular Weight:
1098.36
NACRES:
NA.21

Quality Level

100

Assay

≥95%

form

powder

reaction suitability

reagent type: ligand

mp

154-155 °C

functional group

phosphine

SMILES string

C[Fe]C.FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)c3cccc3)=C1)(F)F.FC(C4=CC(C(F)(F)F)=CC(P(C5=CC(C(F)(F)F)=CC(C(F)(F)F)=C5)c6cccc6)=C4)(F)F

Application

[CF3]8-DPPF is a ferrocenyl phosphine ligand used in a mild Ni catalyzed C-N cross coupling reaction.

Other Notes

The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C–N Cross-Coupling

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Richard Y Liu et al.
Journal of the American Chemical Society, 142(9), 4500-4507 (2020-02-11)
Palladium-catalyzed amination reactions using soluble organic bases have provided a solution to the many issues associated with heterogeneous reaction conditions. Still, homogeneous C-N cross-coupling approaches cannot yet employ bases as weak and economical as trialkylamines. Furthermore, organic base-mediated methods have

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