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796034

Sigma-Aldrich

Graphene oxide

powder, 15-20 sheets, 4-10% edge-oxidized, avg. no. of layers, 15 ‑ 20

Synonym(s):

graphite oxide

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About This Item

Linear Formula:
CxOyHz
UNSPSC Code:
12352103
PubChem Substance ID:
329768525
NACRES:
NA.23

Quality Level

100

form

powder

feature

avg. no. of layers 15 ‑ 20

solubility

water: dispersible (polar solvents)

bulk density

~1.8 g/cm3

SMILES string

O=C(O)C1C2=C3C4=C5C6=C7C8=C9C%10=C%11C(C%12=C%13C%10=C%14C8=C%15C6=C%16C4=C%17C2=CC(C(O)=O)C%18=C%17C%19=C%16C%20=C%15C%21=C%14C%22=C%13C(C%23=C%24C%22=C%25C%21=C%26C%20=C%27C%19=C%28C%18=CC(C(O)=O)C%29=C%28C%30=C%27C%31=C%26C%32=C%25C%33=C%24C(C%34=C%35C

InChI

1S/C140H42O20/c141-131(142)26-13-23-15-44-62(140(159)160)45-16-24-14-40-31(132(143)144)5-1-29-41-20-48(135(149)150)56-33-7-3-28-27-2-6-32-55-37(133(145)146)11-9-35-60(138(155)156)42-17-25-18-43-61(139(157)158)36-10-12-38(134(147)148)58-46-21-50(137(153)154)59-47-22-49(136(151)152)57-34-8-4-30-39(19-26)51(23)78-72(44)88-75(45)80-52(24)79(54(29)40)95-71(41)83(56)101-93-69(33)64(28)91-90-63(27)68(32)92-86(66(35)55)73(42)81-53(25)82-74(43)87(67(36)58)96-76(46)85(59)103-97-77(47)84(57)102-94-70(34)65(30)89(78)105-104(88)115-98(80)111(95)116(101)126-122-110(93)107(91)120-119-106(90)108(92)99(81)114-100(82)112(96)118(103)128(124(114)119)123-113(97)117(102)127(130(122)129(120)123)121(109(94)105)125(115)126/h2,5,7-10,12-22,26,38,48-50H,1,3-4,6,11H2,(H,141,142)(H,143,144)(H,145,146)(H,147,148)(H,149,150)(H,151,152)(H,153,154)(H,155,156)(H,157,158)(H,159,160)

InChI key

VTWITIAIMADGRM-UHFFFAOYSA-N

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General description

  • Form: Brown/Black powder
  • Bulk Density: ~1.8 g/cm3
  • Solubility: Dispersible in water and polar solvents
  • Number of layers: 15-20
  • Oxidation: 4-10%
The material basically consists of exfoliated graphene nanoplatelets containing functional organic groups. The oxygen content is less than 5%; the majority groups are hydroxyls (OH), which enables further chemical modifications to add new functionalities. The functionalization approach was designed to attach most of the groups on the border of the foils, aiming to preserve the intrinsic properties of graphene (e.g.: electric conductivity).

Application

The product is aimed for dispersion and/or incorporation in polar solvents (e.g.: water, THF and DMF) and polar polymeric matrices (e.g.: PLA, PA and PET). It is suitable for in situ polymerization, direct resin mixing and molding, solvent dissolution, extrusion processing after incorporation. Potential applications include:
  • Nanocomposites [1,2]
  • Anti-corrosion coatings [3,4]
  • Films with barrier properties [5,6]
  • Membranes for separation [7,8]
  • Conductive inks [9,10]
  • Energy storage [11,12]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
0000351899
MKCW1866
MKCV8984
0000351899
0000270747

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Graphene oxide, ammonia functionalized 1 mg/mL, dispersion in H2O

Sigma-Aldrich

791520

Graphene oxide, ammonia functionalized

M M Abdel-Mottaleb et al.
Journal of the mechanical behavior of biomedical materials, 96, 118-124 (2019-04-30)
In this work, Polyacrylonitrile nanofibers were enhanced by graphene oxide and zinc oxide, in terms of enhanced the photocatalytic activity and mechanical properties for the composite nanofibers. Photocatalytic degradation of two organic dyes methylene blue dye and indigo carmine dye
Beatriz Salesa et al.
Nanomaterials (Basel, Switzerland), 10(2) (2020-01-30)
Alginate-based materials hold great promise in bioengineering applications such as skin wound healing and scaffolds for tissue engineering. Nevertheless, cell adhesion of mammalian cells on these hydrophilic materials is very poor. In cases such as polycaprolactone, poly(hydroxy-3-butyrate-co-3-valerate) and gelatin, the
Belén Frígols et al.
PloS one, 14(3), e0212819-e0212819 (2019-03-08)
Alginate is considered an exceptional biomaterial due to its hydrophilicity, biocompatibility, biodegradability, nontoxicity and low-cost in comparison with other biopolymers. We have recently demonstrated that the incorporation of 1% graphene oxide (GO) into alginate films crosslinked with Ca2+ cations provides
Transport properties of zigzag graphene nanoribbons with oxygen edge decoration
Zhang CX, et al.
Organic Electronics, 13(11), 2494- 2501 (2012)
Farzaneh Besharat et al.
Nanotechnology, 31(15), 155701-155701 (2019-12-21)
In recent years, in order to obtain improved mechanical, thermal, electrical and barrier/transport properties, aligned carbonaceous nanomaterials/polymer nanocomposite films have been receiving growing attention. Correspondingly, the edge oxidized graphene oxide (EOGO) nanoplatelets alignment influence on the structure of the polyethersulfone
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