767654

cis-Dichlorobis(dimethyl sulfoxide)platinum(II)

97%

• Synonym(s): cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)₂Cl₂
• Empirical Formula (Hill Notation): C₄H₁₂Cl₂O₂PtS₂
• CAS Number: 22840-91-1
• Molecular Weight: 422.25
• MDL number: MFCD00061452
• UNSPSC Code: 12161600
• PubChem Substance ID: 329767328
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 97%
• form: solid
• reaction suitability: core: platinum; reagent type: catalyst
• mp: 218-224 °C
• SMILES string: Cl[Pt]Cl.CS(C)=O.CS(C)=O
• InChI: 1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
• InChI key: KDADQDWVKZJTDQ-UHFFFAOYSA-L

Description

General description

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst.

Application

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:

• Catalyst in the oleum-mediated (SO₃-H₂SO₄) methane oxidation to form methyl bisulfate (MBS).
• Precursor in the synthesis of cyclometalated complexes.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable