692794

(S,S)-DACH-phenyl Trost ligand

95%

• Synonym(s): (1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl)
• Empirical Formula (Hill Notation): C₄₄H₄₀N₂O₂P₂
• CAS Number: 169689-05-8
• Molecular Weight: 690.75
• MDL number: MFCD01631274
• UNSPSC Code: 12352002
• PubChem Substance ID: 329761528
• NACRES: NA.06

Properties

• Assay: 95%
• form: solid
• optical activity: [α]20/D -134°, c = 1 in methanol
• mp: 136-142 °C
• functional group: amide; phosphine
• SMILES string: O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
• InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1
• InChI key: AXMSEDAJMGFTLR-ZAQUEYBZSA-N

Description

Application

Trost Ligands for Asymmetric Allylic Alkylation

Asymmetric allylic alkylation ligand.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves