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559873

Sigma-Aldrich

Dess-Martin periodinane solution

0.3 M in methylene chloride

Synonym(s):

1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one, Dess-Martin reagent, Triacetoxyperiodinane

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

reagent type: oxidant

concentration

0.3 M in methylene chloride

bp

40 °C

density

1.369 g/mL at 25 °C

functional group

iodo

storage temp.

2-8°C

SMILES string

CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12

InChI

1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3

InChI key

NKLCNNUWBJBICK-UHFFFAOYSA-N

Application

Widely used reagent for the mild oxidation of alcohols to aldehydes and ketones.

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Dess, D. B.; Martin, J. C.
The Journal of Organic Chemistry, 48, 4155-4155 (1983)

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