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531960

Sigma-Aldrich

(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride

Synonym(s):

(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminium(III) chloride

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About This Item

Empirical Formula (Hill Notation):
C36H52AlClN2O2
CAS Number:
Molecular Weight:
607.24
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

mp

250-255 °C (lit.)

Quality Level

SMILES string

CC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1

InChI key

KGVBCKDZFMLRMA-OHRASPNLSA-K

Application

Catalyst for:
  • Asymmetric iodolactonizations
  • Cyanosilylation reactions
  • Phospho-aldol catalysis

Legal Information

Sold under license from Sterling Pharma Solutions Limited.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Articles

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The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

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