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462268

Sigma-Aldrich

4,4′-Diamino-2,2′-stilbenedisulfonic acid

technical grade, 85%

Synonym(s):

Amsonic acid

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About This Item

Empirical Formula (Hill Notation):
C14H14N2O6S2
CAS Number:
Molecular Weight:
370.40
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Assay

85%

mp

>300 °C (lit.)

functional group

sulfonic acid

SMILES string

Nc1ccc(\C=C\c2ccc(N)cc2S(O)(=O)=O)c(c1)S(O)(=O)=O

InChI

1S/C14H14N2O6S2/c15-11-5-3-9(13(7-11)23(17,18)19)1-2-10-4-6-12(16)8-14(10)24(20,21)22/h1-8H,15-16H2,(H,17,18,19)(H,20,21,22)/b2-1+

InChI key

REJHVSOVQBJEBF-OWOJBTEDSA-N

General description

Disodium salt of 4,4′-diamino-2,2′-stilbenedisulfonic acid may be used in the synthesis of dyes and optical brighteners or fluorescent whitening agents.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Organic ultraviolet (UV) rays absorbents have been used as sunscreen materials, but they may pose a safety problem when used at high concentration. In order to prevent direct contact of organic UV rays absorbent to the human skin, a typical
Z Li et al.
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H acid and DSD acid are two important substrate of dyes, which wastewater is treated more difficulty because of containing multi-component, with high chroma value and nonbiodegradability. A treatment way of this wastewater by extraction based on chemical association was
K A Hostetler et al.
Journal of toxicology and environmental health, 48(2), 141-149 (1996-06-07)
4,4'-Diamino-2,2'-stilbene disulfonic acid (DAS), a key intermediate in the synthesis of dyes and fluorescent whitening agents, has been purported to have weak estrogenic properties based on apparent structural similarity with diethylstibestrol (DES) and unsubstantiated reports of male reproductive dysfunction in
C J Venglarik et al.
Molecular and cellular biochemistry, 140(2), 137-146 (1994-11-23)
We showed previously that the disulfonic stilbene DNDS (4,4'-dinitrostilben-2,2'-disulfonic acid) was a potent blocker of outwardly rectifying chloride channels (ORCC). The studies reported here were designed to quantify the relationship between electron withdrawal by the 4,4'-substituents and blocker potency. Specifically
G Yu et al.
Chemosphere, 37(3), 487-494 (1998-07-14)
Two advanced oxidation processes, Fenton's reagent oxidation and ozonation, were used for pretreatment of a 4,4'-diaminostilbene-2,2'-disulfonic acid (DSD-acid) manufacturing wastewater on a laboratory scale. The results showed that both methods are suitable for partial removal of chemical oxygen demand (COD)

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