452807
Trichloro(3,3,3-trifluoropropyl)silane
97%
Synonym(s):
3,3,3-Trifluoropropyl-trichlorosilane
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About This Item
Linear Formula:
CF3CH2CH2SiCl3
CAS Number:
Molecular Weight:
231.50
Beilstein:
1748876
EC Number:
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
refractive index
n20/D 1.386 (lit.)
bp
114 °C (lit.)
density
1.419 g/mL at 25 °C (lit.)
functional group
fluoro
SMILES string
FC(F)(F)CC[Si](Cl)(Cl)Cl
InChI
1S/C3H4Cl3F3Si/c4-10(5,6)2-1-3(7,8)9/h1-2H2
InChI key
WEUBQNJHVBMUMD-UHFFFAOYSA-N
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Application
Trichloro(3,3,3-trifluoropropyl)silane can be used as a precursor for the preparation of:
It can also be used as a silanizing agent to coat the inner surface of pipettes in order to investigate the electrical charging of droplets discharged from the micropipette.
- Fluorinated polyhedral oligomeric silsesquioxane (F-POSS) by base-catalyzed condensation.
- 3,3,3-Trifluoropropyltrimethoxysilane by alcoholysis reaction with methanol.
It can also be used as a silanizing agent to coat the inner surface of pipettes in order to investigate the electrical charging of droplets discharged from the micropipette.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
113.7 °F - closed cup - (own results)
Flash Point(C)
45.4 °C - closed cup - (own results)
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Dongwhi Choi et al.
Scientific reports, 3, 2037-2037 (2013-06-21)
We report that a droplet dispensed from a micropipette almost always has a considerable electrical charge of a magnitude dependent on the constituents of the droplet, on atmospheric humidity and on the coating material of pipette tip. We show that
Scott T Iacono et al.
Chemical communications (Cambridge, England), (47), 4992-4994 (2007-12-01)
New fluorinated polyhedral oligomeric silsesquioxane (F-POSS) structures possessing a high degree of hydrophobicity have been prepared via a facile corner-capping methodology.
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Journal of Visualized Experiments, 77, e50438-e50438 (2013)
Kyung Won Ro et al.
Electrophoresis, 24(18), 3253-3259 (2003-10-01)
Capillary electrochromatography (CEC) and preconcentration of neutral compounds have been realized on poly(dimethylsiloxane) (PDMS) microchips. The channels are coated with polyelectrolyte multilayers to avoid absorption of hydrophobic analytes into PDMS. The structures of a microchip include an injector and a
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Synt. Metals, 146(3), 325-328 (2004)
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