442585

Pentafluorophenylmagnesium bromide solution

0.5 M in diethyl ether

• Synonym(s): (Perfluorophenyl)magnesium bromide, 2,3,4,5,6-Pentafluorophenylmagnesium bromide, Bromo(pentafluorophenyl)magnesium
• Linear Formula: C₆F₅MgBr
• CAS Number: 879-05-0
• Molecular Weight: 271.27
• Beilstein: 3611565
• MDL number: MFCD00015720
• UNSPSC Code: 12352103
• PubChem Substance ID: 24867918
• NACRES: NA.22

Properties

• form: liquid
• reaction suitability: reaction type: Grignard Reaction
• concentration: 0.5 M in diethyl ether
• bp: 34.6 °C
• density: 0.861 g/mL at 25 °C
• functional group: fluoro
• SMILES string: Fc1c(F)c(F)c([Mg]Br)c(F)c1F
• InChI: 1S/C6F5.BrH.Mg/c7-2-1-3(8)5(10)6(11)4(2)9;;/h;1H;/q;;+1/p-1
• InChI key: AXQVMJIDNDRSFM-UHFFFAOYSA-M

Description

Application

Employed in the synthesis of novel arsonic and arsinic acids as ligands for potential transition-metal ion extractants, and in the synthesis of polyfluoroaryl alkyl sulfides.

Safety Information

• Pictograms: GHS02,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H224,H302,H314,H336
• Precautionary Statements: P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Central nervous system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): -40.0 °F - closed cup
• Flash Point(C): -40 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves