345296
Poly(tetrahydrofuran)
average Mn ~1,000
Synonym(s):
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), polyTHF
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All Photos(2)
About This Item
Linear Formula:
H(OCH2CH2CH2CH2)nOH
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
vapor pressure
<0.01 mmHg ( 25 °C)
<1 mmHg ( 20 °C)
Quality Level
mol wt
average Mn ~1,000
contains
0.05-0.07% BHT as stabilizer
mp
25-33 °C
density
0.974 g/mL at 25 °C
SMILES string
OCCCCO
InChI
1S/C8H18O2/c1-3-5-6-10-8(4-2)7-9/h8-9H,3-7H2,1-2H3/t8-/m0/s1
InChI key
BJZYYSAMLOBSDY-QMMMGPOBSA-N
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Application
Poly(tetrahydrofuran) can be used as a starting material to prepare:
- Thermally reversible urethane -epoxy networks.
- Poly(hexamethylene 2,6-naphthalate)-block-poly(tetrahydrofuran) (PHN-b-N-pTHF) copolymers with shape memory effect via melt polycondensation.
- Poly(3,4-ethylenedioxythiophene):poly(tetrahydrofuran) composite for the fabrication of memory organic electrochemical transistors.
Features and Benefits
- High flexibility
- Hydrolytic stability
- Excellent abrasion resistance
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
>325.4 °F - Tag open cup
Flash Point(C)
> 163 °C - Tag open cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M Renier et al.
Journal of biomaterials science. Polymer edition, 5(3), 231-244 (1993-01-01)
Poly(etherurethane urea) (PEUU) elastomers when employed as biomedical devices may be susceptible to extraction upon implantation. Four PEUU elastomers containing a single PEUU formulation, but varying in terms of their additives, were subjected to an in vitro extraction procedure. The
K Y Chen et al.
Journal of biomaterials science. Polymer edition, 10(12), 1183-1205 (2000-02-15)
Two novel aliphatic polyurethaneurea anionomers were synthesized based on polydimethylsiloxane (PDMS)-polytetramethylene oxide (PTMO) soft segments. The hard segments consisted of either 4,4'-methylene dicyclohexyl diisocyanate (H12MDI), sulfonic acid-containing diol and 1,4-butandiol (BD) or H12MDI, carboxylic acid-containing diol and BD. The nonionic
R Nakaoka et al.
Journal of biomedical materials research, 49(1), 99-105 (1999-11-24)
Interaction of macrophages (Mos) with polyetherurethane (PEU) was investigated to clarify the role of the Mos in the early stage of tumorigenesis of PEUs. As for the inflammatory cytokines produced from Mos, the amount of tumor necrosis factor (TNF) produced
A Brandwood et al.
Journal of biomaterials science. Polymer edition, 6(1), 41-54 (1994-01-01)
A series of novel polyurethane elastomers based on methylenediphenyl diisocyanate, 1,4-butanediol and the macrodiols, poly(hexamethylene oxide), poly(octamethylene oxide), and poly(decamethylene oxide) were implanted subcutaneously in sheep for periods of 3 and 6 months. The specimens that were subjected to 3
P Banu et al.
Journal of colloid and interface science, 277(2), 304-308 (2004-09-03)
Aqueous dispersions of poly(ester-imide)s [P(E-I)s] have been prepared by dispersing the P(E-I)s in water without any external solubilizing agents. P(E-I)s were prepared from anhydride-terminated polyester prepolymer and diisocyanate. The -COOH groups in the polymer were then neutralized using triethylamine and
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