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335150

Sigma-Aldrich

Phenylsilane

97%

Synonym(s):

Monophenylsilane

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About This Item

Linear Formula:
C6H5SiH3
CAS Number:
694-53-1
Molecular Weight:
108.21
Beilstein:
2935169
EC Number:
211-772-5
MDL number:
MFCD00013478
UNSPSC Code:
12352103
PubChem Substance ID:
24860291
NACRES:
NA.22

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.510 (lit.)

bp

120 °C (lit.)

density

0.877 g/mL at 25 °C (lit.)

SMILES string

[SiH3]c1ccccc1

InChI

1S/C6H8Si/c7-6-4-2-1-3-5-6/h1-5H,7H3

InChI key

PARWUHTVGZSQPD-UHFFFAOYSA-N

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Application

Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

46.4 °F - closed cup

Flash Point(C)

8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW3777
SHBR6109
SHBN4943
SHBH2620V
SHBH0006V

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Xiaoyan Yin et al.
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Lipidated peptide amphiphiles exhibit high affinity for plasma cell membranes, good cell internalization and improved stability against degradation, which make them attractive as a drug delivery system. However, low drug loading capacity limits their application for drug delivery. Herein, we
Tadhg Kennedy et al.
ACS nano, 9(7), 7456-7465 (2015-07-01)
Here we report the rational design of a high-capacity Li-ion anode material comprising Ge nanowires with Si branches. The unique structure provides an electrode material with tunable properties, allowing the performance to be tailored for either high capacity or high
Photopolymerization of Methyl methacrylate with Phenylsilane.
Hong L-Y
Bull. Korean Chem. Soc., 16(4), 360-363 (1995)
The Role of Precursor?Decomposition Kinetics in Silicon?Nanowire Synthesis in Organic Solvents.
Lee DC
Angewandte Chemie (International Edition in English), 44(23), 3573-3577 (2005)
Chayanon Ngambenjawong et al.
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Peptide cyclization is a strategy used to improve stability and activity of peptides. The most commonly used cyclization method is disulfide bridge formation of cysteine-containing peptides, as is typically found in nature. Over the years, an increasing number of alternative
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