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Key Documents

226157

Sigma-Aldrich

N-Boc-hydroxylamine

≥98%

Synonym(s):

tert-Butyl N-hydroxycarbamate

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About This Item

Linear Formula:
(CH3)3COCONHOH
CAS Number:
Molecular Weight:
133.15
Beilstein:
1756546
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

≥98%

form

solid

mp

53-55 °C (lit.)

functional group

amine

storage temp.

2-8°C

SMILES string

CC(C)(C)OC(=O)NO

InChI

1S/C5H11NO3/c1-5(2,3)9-4(7)6-8/h8H,1-3H3,(H,6,7)

InChI key

DRDVJQOGFWAVLH-UHFFFAOYSA-N

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Related Categories

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Useful hydroxylamine derivatives for the synthesis of hydroxamic acids.
Tetrahedron Letters, 33(35), 5055-5058 (1992)
Tetrahedron Letters, 33, 5055-5055 (1992)
Synthetic Communications, 22, 2579-2579 (1992)
Brian S Bodnar et al.
The Journal of organic chemistry, 72(10), 3929-3932 (2007-04-14)
The addition of azides to acylnitroso hetero-Diels-Alder cycloadducts derived from cyclopentadiene affords exo-triazolines in excellent yield. The reaction is greatly affected by the level of alkene strain, while sterically demanding azides do not hinder the reaction. Conversion of the triazolines
M J Lee et al.
Journal of medicinal chemistry, 35(20), 3648-3652 (1992-10-02)
In the preceding paper, analogs of chlorpropamide with an OMe substituent on the sulfonamide nitrogen were shown to inhibit aldehyde dehydrogenase (AlDH), and it was postulated that these compounds were bioactivated by O-demethylation to release nitroxyl (HN = O, nitrosyl

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