174653
Triethyl 2-phosphonopropionate
98%
Synonym(s):
2-(Diethoxyphosphoryl)propionic acid ethyl ester
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Assay
98%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.431 (lit.)
bp
143-144 °C/12 mmHg (lit.)
density
1.111 g/mL at 25 °C (lit.)
functional group
ester
phosphonate
SMILES string
CCOC(=O)C(C)P(=O)(OCC)OCC
InChI
1S/C9H19O5P/c1-5-12-9(10)8(4)15(11,13-6-2)14-7-3/h8H,5-7H2,1-4H3
InChI key
BVSRWCMAJISCTD-UHFFFAOYSA-N
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Application
Reactant involved in:
- Intramolecular conjugate addition for the synthesis of floresolide B
- Chemoenzymatic one-pot synthesis of γ-butyrolactones
- Enantioselective synthesis of spiroindane di-Me acetic acid via asymmetric hydrogenation
- Stereoselective intramolecular Diels-Alder reactions
- Horner-Wadsworth-Emmons reactions
This Wittig-Horner reagent condenses with a wide variety of aldehydes and ketones to form acrylates.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
192.2 °F - closed cup
Flash Point(C)
89 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthetic Communications, 21, 17-17 (1991)
Tetrahedron, 48, 10327-10327 (1992)
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