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F5879

Sigma-Aldrich

Ammonium iron(III) citrate

reagent grade, powder

Synonym(s):

Ammonium ferric citrate, Ferric ammonium citrate

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About This Item

Linear Formula:
C6H8O7 ·xFe3+ · yNH3
CAS Number:
EC Number:
UNSPSC Code:
12352300
eCl@ss:
38190508
PubChem Substance ID:
NACRES:
NA.55

grade

reagent grade

form

powder

composition

Iron, 16.5-18.5%

cation traces

Fe: 16.5-18.5%

SMILES string

N.OC12CC(=O)O[Fe](OC(=O)C1)OC(=O)C2

InChI

1S/C6H8O7.Fe.H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;1H3/q;+3;/p-3

InChI key

FRHBOQMZUOWXQL-UHFFFAOYSA-K

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General description

Ammonium iron(III)citrate can be used as a reagent and iron precursor in several organic reactions and Fe3O4-based nanomaterial preparation. It can be prepared by treating Fe(OH)3 with citric acid and NH4OH in various ratios.

Application

Ammonium iron(III) citrate can be used as a reagent to prepare amphiphilic siderophore iron acinetoferrin complex from acinetoferrin in the presence of HEPES (4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid) buffer. It can also be used as an iron precursor to prepare Fe3O4-carbon dots magnetic-fluorescent hybrid nanoparticles.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Pengfei Wang et al.
Science advances, 5(4), eaau8038-eaau8038 (2019-04-17)
The in situ measurement of the distribution of biomolecules inside a cell is one of the important goals in life science. Among various imaging techniques, magnetic imaging (MI) based on the nitrogen-vacancy (NV) center in diamond provides a powerful tool
Yulia Pollak et al.
Journal of neural transmission (Vienna, Austria : 1996), 120(1), 37-48 (2012-03-27)
Iron accumulation and iron-related oxidative stress are involved in several pathological conditions and provide a rationale for the development of iron chelators as novel promising therapeutic strategies. Thus, we have recently synthesized multifunctional non-toxic, brain permeable iron chelating compounds, M30
Shounak Baksi et al.
Scientific reports, 7(1), 12843-12843 (2017-10-11)
Retinal degeneration is prominent in Parkinson's disease (PD), a neuromotor disorder associated with aggregation of α-synuclein (α-syn) in the substantia-nigra (SN). Although α-syn is expressed in the neuroretina, absence of prominent aggregates suggests altered function as the likely cause of
Luca Valenti et al.
Arteriosclerosis, thrombosis, and vascular biology, 31(3), 683-690 (2010-12-25)
Increased body iron stores and hepcidin have been hypothesized to promote atherosclerosis by inducing macrophage iron accumulation and release of cytokines, but direct demonstration in human cells is lacking. The aim of this study was to evaluate the effect of
Jaya P Gnana-Prakasam et al.
Investigative ophthalmology & visual science, 52(6), 3751-3758 (2011-03-02)
GPR91, a succinate receptor, is expressed in retinal ganglion cells and induces vascular endothelial growth factor (VEGF) expression. RPE also expresses VEGF, but whether this cell expresses GPR91 is not known. Excessive iron is also proangiogenic, and hemochromatosis is associated

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