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Key Documents

05-2170

Sigma-Aldrich

Ammonium cerium(IV) nitrate

JIS special grade, ≥95.0%

Synonym(s):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
Molecular Weight:
548.22
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

grade

JIS special grade

Assay

≥95.0%

form

crystalline

availability

available only in Japan

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Weibin Song et al.
Bioorganic & medicinal chemistry letters, 22(1), 387-390 (2011-11-26)
A new, practical and efficient method for the synthesis of anhydrovinblastine AVBL (1f) by oxidative coupling of vindoline and catharanthine in the presence of ceric ammonium nitrate (CAN) was developed. Under the optimized reaction conditions, we synthesized a new series
D Subhas Bose et al.
Journal of combinatorial chemistry, 12(1), 100-110 (2009-12-17)
An efficient and practical method has been manifested for the diversity-oriented synthesis of quinolines via Friedländer annulation reaction for the generation of a wide range of structurally interesting and pharmacologically significant compounds by using ceric ammonium nitrate as a catalyst
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
Yue Qi Ye et al.
Bioscience, biotechnology, and biochemistry, 74(11), 2342-2344 (2010-11-13)
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation
Amit H Haviv et al.
Journal of the American Chemical Society, 132(36), 12519-12521 (2010-08-26)
The high-power ultrasonic irradiation of preformed magnetite (Fe(3)O(4)) nanoparticles in the presence of monoelectronic Ce-containing ceric ammonium nitrate [Ce(IV)(NH(4))(2)(NO(3))(6)] oxidant in MeCOMe afforded hydrophilic 50 nm-sized colloidal, highly stable maghemite (gamma-Fe(2)O(3)) nanoparticles. An "inorganic" Ce atom doping of the NP

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