8.22340
Phosphorus pentachloride
for synthesis
Synonym(s):
Phosphorus pentachloride, Phosphorus(V) chloride
About This Item
vapor pressure
0.016 hPa ( 20 °C)
Quality Level
Assay
≥99.0% (argenometric)
form
crystalline solid
potency
660 mg/kg LD50, oral (Rat)
pH
1 (5 g/L in H2O, acidic)
mp
148 °C
density
2.1 g/cm3 at 20 °C
storage temp.
2-30°C
InChI
1S/Cl5P/c1-6(2,3,4)5
InChI key
UHZYTMXLRWXGPK-UHFFFAOYSA-N
Application
- Phosphorylation of Glycoluryl Derivatives: New organoelement phosphorus derivatives synthesized using glycoluril and phosphorus pentachloride under controlled conditions (Salkeeva et al., 2021).
- Alcohol Amination and Cyclization: Catalyzed alcohol amination of diethanolamine by a Ru-PNP Pincer complex using phosphorus pentachloride to produce piperazine, demonstrating high conversion rates (van der Loo et al.).
- Chemical Weapons Convention Relevance: Rapid GC-MS screening of chlorides relevant to the Chemical Weapons Convention, including phosphorus pentachloride, for monitoring prohibited chemical activities (Kuitunen et al., 2020).
- Silicon Nanocrystal Functionalization: Phosphorus pentachloride used for the functionalization of silicon nanocrystals, enhancing their utility in advanced materials applications (Islam et al., 2017).
Analysis Note
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
Target Organs
Respiratory Tract
Supplementary Hazards
Storage Class Code
6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
Certificates of Analysis (COA)
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