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335150

Sigma-Aldrich

Phenylsilane

97%

Synonym(s):

Monophenylsilane

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About This Item

Linear Formula:
C6H5SiH3
CAS Number:
694-53-1
Molecular Weight:
108.21
Beilstein:
2935169
EC Number:
211-772-5
MDL number:
MFCD00013478
UNSPSC Code:
12352103
PubChem Substance ID:
24860291
NACRES:
NA.22

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.510 (lit.)

bp

120 °C (lit.)

density

0.877 g/mL at 25 °C (lit.)

SMILES string

[SiH3]c1ccccc1

InChI

1S/C6H8Si/c7-6-4-2-1-3-5-6/h1-5H,7H3

InChI key

PARWUHTVGZSQPD-UHFFFAOYSA-N

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Application

Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

46.4 °F - closed cup

Flash Point(C)

8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of poly (arylene phosphine oxide) by nickel-catalysed coupling polymerization.
Ghassemi H
Polymer, 38(12), 3139-3143 (1997)
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This work presents the selection and characterization of erythropoietin (EPO)-binding cyclic peptide ligands. The sequences were selected by screening a focused library of cyclic depsipeptides cyclo[(N
Grace Flynn et al.
Nano letters, 16(1), 374-380 (2015-12-18)
Herein, we report the formation of multisegment Si-Ge axial heterostructure nanowires in a wet chemical synthetic approach. These nanowires are grown by the liquid injection of the respective silicon and germanium precursors into the vapor phase of an organic solvent
The Role of Precursor?Decomposition Kinetics in Silicon?Nanowire Synthesis in Organic Solvents.
Lee DC
Angewandte Chemie (International Edition in English), 44(23), 3573-3577 (2005)
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