209058
Rhodium(II) acetate dimer
powder
Synonym(s):
Rh2(OAc)4, Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
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About This Item
Linear Formula:
Rh2(OOCCH3)4
CAS Number:
Molecular Weight:
441.99
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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form
powder
Quality Level
reaction suitability
core: rhodium
reagent type: catalyst
SMILES string
CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
InChI
1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
InChI key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
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General description
Rhodium(II) acetate dimer is an effective catalyst for carbenoid reactions, hydrocarbon oxidation, hydroboration, and nitrene reactions.[1]
Application
Effective catalyst for ylide formation.
Homogeneous catalyst.[2]
Used in an efficient synthesis of ß-hydroxy-α-arylacrylates involving the decomposition of diazoetster intermediates with concomitant 1,2-arylmigration.[3]
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Dirhodium(II) Tetraacetate
Michael P, et al.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Aldrichimica Acta, 15, 13-13 (1982)
Sugimura, T.; Mori, A.
Tetrahedron Asymmetry, 14, 881-881 (2003)
Carter, D.S. Van Vranken, D.L.
Tetrahedron Letters, 40, 1617-1617 (1999)
Zhaohui Qu et al.
The Journal of organic chemistry, 69(1), 217-219 (2004-01-03)
The relative rate constants for the Rh(II)-catalyzed insertion of diazoacetone into the O-H bond have been measured through intermolecular competitions. The kinetic data were subjected to Hammett correlation analysis, and mechanistic implication of the results with respect to a stepwise
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