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15338

Sigma-Aldrich

Lead(II) oxide

puriss. p.a., ≥99.0% (KT), yellow

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About This Item

Linear Formula:
PbO
CAS Number:
Molecular Weight:
223.20
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.21

vapor pressure

10 mmHg ( 0 °C)

grade

puriss. p.a.

Assay

≥99.0% (KT)

form

powder

impurities

≤0.001% total nitrogen (N)

color

yellow

pH

9.9 (20 °C, 100 g/L)

mp

886 °C (lit.)

anion traces

chloride (Cl-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤10 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES string

O=[PbH2]

InChI

1S/O.Pb

InChI key

YEXPOXQUZXUXJW-UHFFFAOYSA-N

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General description

Lead(II) oxide exists in two forms: red, tetragonal PbO and yellow rhombic PbO. It is amphoteric in nature but basic character is more prominent. It reacts with water and carbon dioxide to form basic lead(II) carbonate. Industrial preparation of PbO is by oxidation of molten lead with O2 or thermal decomposition of lead(II) nitrate, carbonate or hydroxide.1
Lead(II) oxide is a crystalline solid, which can be prepared by decomposition of lead carbonate or by heating molten lead in the presence of air. It can be used in the synthesis of lead(II) ethanoate by reaction with ethanoic acid.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Lact. - Repr. 1A - STOT RE 1

Target Organs

Central nervous system,Kidney,Blood

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of 3-O-methylgallic acid a powerful antioxidant by electrochemical conversion of syringic acid.
Gargouri OD, Gargouri B, Trabelsi SK, et al.
Biochimica et Biophysica Acta, 1830(6), 3643-3649 (2013)
Dhingra A
The Sterling Dictionary Of Chemistry (1999)
Gerrans.C.G, et al
Sasol Encyclopaedia of Science and Technology (2004)
Hui Lin et al.
Water research, 46(7), 2281-2289 (2012-03-03)
Electrochemical decomposition of environmentally persistent perfluorooctanoic acid (PFOA) in aqueous solution was investigated over Ti/SnO(2)-Sb, Ti/SnO(2)-Sb/PbO(2), and Ti/SnO(2)-Sb/MnO(2) anodes. The degradation of PFOA followed pseudo-first-order kinetics. The degradation ratios on Ti/SnO(2)-Sb, Ti/SnO(2)-Sb/PbO(2), and Ti/SnO(2)-Sb/MnO(2) anodes achieved 90.3%, 91.1%, and 31.7%
J Berashevich et al.
Journal of physics. Condensed matter : an Institute of Physics journal, 25(7), 075803-075803 (2013-01-24)
The electronic properties of polycrystalline lead oxide consisting of a network of single-crystalline α-PbO platelets and the formation of native point defects in the α-PbO crystal lattice are studied using first-principles calculations. The results suggest that the polycrystalline nature of

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