ALD00632
Methyl (-)-PI Reagent
≥95%
Synonym(s):
1,3,2-Benzoxathiaphosphole, hexahydro-2,7a-dimethyl-5-(1-methylethenyl)-, 2-sulfide, (2S,3aS,5R,7aS)
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About This Item
Empirical Formula (Hill Notation):
C11H19OPS2
CAS Number:
Molecular Weight:
262.37
UNSPSC Code:
12352005
NACRES:
NA.06
Recommended Products
Quality Level
Assay
≥95%
form
powder
storage temp.
2-8°C
SMILES string
[H][C@@]1(S[P@](O2)(C)=S)[C@]2(C)CC[C@@H](C(C)=C)C1
Application
Methyl (-)-PI Reagent is a methyl substituted analog of the air and moisture-tolerant (-)-PI reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides.
Learn more about PI and PSI reagents
Learn more about PI and PSI reagents
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Dongmin Xu et al.
Journal of the American Chemical Society, 142(12), 5785-5792 (2020-02-29)
Phosphorus Incorporation (PI, abbreviated Π) reagents for the modular, scalable, and stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides are reported. Synthesized from trans-limonene oxide, this reagent class displays an unexpected reactivity profile and enables access to chemical space distinct
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