Skip to Content
MilliporeSigma
All Photos(1)

Documents

925721

Sigma-Aldrich

9-(1-Naphthalenyl)-10-(4-(2-naphthalenyl)phenyl)anthracene

≥97%

Synonym(s):

BH

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C40H26
CAS Number:
Molecular Weight:
506.63
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23

description

PL: 421 nm, 468 nm

Quality Level

Assay

≥97%

form

powder

color

white

Orbital energy

HOMO 5.68 eV 
LUMO 2.68 eV 

UV absorption

λ: 357 nm Amax
λ: 375 nm Amax
λ: 395 nm Amax

storage temp.

2-8°C

Application

9-(1-Naphthalenyl)-10-(4-(2-naphthalenyl)phenyl)anthracene (BH) could be used as a blue host in the fabrication of blue OLED device. BH is a host material with a high molecular weight and a great steric hindrance by introducing bulky aromatic rings and rigid cardo structure, and BH have a high thermal stability (Tg of 131 °C; Tm of 274 °C; and Td of 367 °C).

With a ET of 1.50 eV, BH is a very popular blue fluorescent host material due to its large band gap (Eg = 3.0 eV).

OLED Device Performance

1. Ag (100 nm)/TBPDA: TECTFCNBN(97:3,10 nm)/TBPDA (z nm)/BDFTPA (10 nm)/BH: BDFDPPDA (95:5, 20 nm)/NAPIZ: LiQ (50:50, 35 nm)/Yb (1.5 nm)/Ag:Mg = 9:1 (16 nm)/TBPDA (65 nm).
Color: blue
CIEx,y: (0.1400, 0.0399)
Blue index: 139.9
Current efficiency: 5.58 Cd/A

2. ITO/HATCN (5 nm)/DBPTPPB(100 nm)/TPN-DBF (10 nm)/BH:BTBF-DPh = 25:1 (40 nm)/ANT-BIZ (40 nm)/Liq (2.5 nm)/Al (100 nm)
Color: blue
CIEx,y: (0.151, 0.069)
Max. CE: 2.96 Cd/A
Max. EQE: 4.23 %

3. ITO (150 nm)/HAT-CN (10 nm)/TBPDIA (60 nm)/DFBDDbA (10 nm)/BH:BD (5 wt%) (25 nm)/NAPI:LiQ = 1:1 (35 nm)/Al (80 nm).
Color: blue
CIEx,y: (0.1288, 0.1581)
Lifetime: 277 h at 10 mA cm-2
Max. EQE: 7.15 %
Max. CE: 8.52 Cd/A

4. ITO/HATCN (5 nm)/LHT001 (30 nm)/LEB001 (5 nm)/BD (10%):BH (20 nm)/LET003 (30 nm)/Liq (2 nm)/Al and nondoped structure ITO/HATCN (5 nm)/NPB (50 nm)/BD (20 nm)/LET003 (30 nm)/Liq (2 nm)/Al
Color: blue
CIEx,y: (0.16, 0.06)
Max. EQE: 4.01 %
Max. CE: 3.09 Cd/A
Max. PE: 2.56 Cd/A
EL FWHM: 51 nm
9-(1-Naphthalenyl)-10-(4-(2-naphthalenyl)phenyl)anthracene is a fluorescent organic compound used as a hole transport layer or an emissive layer in OLED devices, organic photovoltaics (OPVs), organic field-effect transistors (OFETs) and perovskite solar cells.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Fabrication of highly efficient blue top-emission organic light-emitting diodes on different reflective electrodes.
Ci Z, et al.
Organic Electronics, 95, 106197-106197 (2021)
Multifunctional Benzo[4,5]thieno[3,2-b]benzofuran Derivative with High Mobility and Luminescent Properties.
Wang J, et al.
ACS Applied Materials & Interfaces, 13, 12250-12258 (2021)
Electron blocking materials based on dimethyl-dihydrobenzofuran derivatives for highly efficient and long-lifetime blue fluorescent organic light-emitting diodes.
Hu B, et al.
Organic Electronics, 87, 105916-105916 (2020)
Anthracene derivatives as highly efficient deep-blue emitters with extremely low driving voltages, Von ≤2.7 V
Qiu F, et al.
Dyes and Pigments, 180, 108458-108458 (2020)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service