763004

CPhos Pd G3

95%

• Synonym(s): CPhos-G3-Palladacycle, CPhos-Pd-G3, [(2-Dicyclohexylphosphino-2′,6′-bis(N,N-dimethylamino) -1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate
• Empirical Formula (Hill Notation): C₄₁H₅₄N₃O₃PPdS
• CAS Number: 1447963-73-6
• Molecular Weight: 806.34
• UNSPSC Code: 12161600
• PubChem Substance ID: 329767018
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• form: solid
• feature: generation 3
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• mp: 176-178 °C (decomposition)
• functional group: phosphine
• SMILES string: CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CN(C)c3cccc(N(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6
• InChI: 1S/C28H41N2P.C12H10N.CH4O3S.Pd/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-23H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
• InChI key: SMFSVINURNWOPR-UHFFFAOYSA-M

Description

General description

CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable