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664995

Sigma-Aldrich

Chlorodihydrido[bis(2-diisopropylphosphino)ethylamine]iridium(III), mixture of isomers

97%

Synonym(s):

[2-[bis(1-methylethyl)phosphino-KP]-N-[2-[bis(1-methylethyl)phosphino-KP]ethyl]ethanamine-KN]chlorodihydroiridium

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About This Item

Empirical Formula (Hill Notation):
C16H39ClIrNP2
Molecular Weight:
535.11
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: iridium
reagent type: catalyst

mp

248-253 °C

SMILES string

Cl[IrH2].CC(C)P(CCNCCP(C(C)C)C(C)C)C(C)C

InChI

1S/C16H37NP2.ClH.Ir.2H/c1-13(2)18(14(3)4)11-9-17-10-12-19(15(5)6)16(7)8;;;;/h13-17H,9-12H2,1-8H3;1H;;;/q;;+1;;/p-1

InChI key

QPAONQONOKDMMJ-UHFFFAOYSA-M

Application

Catalyst for:
  • Preparation of aliphatic amine derivatives via amination of alcohols and diols with amines
  • Hydrogenation of ketones, diketones, unsaturated ketones and aldehydes

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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