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Sigma-Aldrich

Rhenium(VII) oxide

≥99.9% trace metals basis

Synonym(s):

Dirhenium heptoxide, Rhenium heptoxide

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About This Item

Linear Formula:
Re2O7
CAS Number:
Molecular Weight:
484.41
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: rhenium
reagent type: catalyst

bp

360 °C (lit.)

mp

220 °C (lit.)

density

6.103 g/mL at 25 °C (lit.)

SMILES string

O=[Re](=O)(=O)O[Re](=O)(=O)=O

InChI

1S/7O.2Re

InChI key

NBGOSNNAAHDRLK-UHFFFAOYSA-N

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Application

Precursor to organorhenium oxides which catalyze olefin oxidation, metathesis and other transformations.
Reagents used for dehydrations and rearrangements of allylic alcohols, oximes, and amides; oxidative cyclizations; alkene metathesis; formation of bisperoxyacetals; reductions.

Features and Benefits

Precursor to organorhenium oxides which catalyze olefin oxidation, metathesis and other transformations.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Herrmann, W.A. et al.
Inorganic Chemistry, 34, 4701-4701 (1995)
Rhenium(VII) Oxo and Imido Complexes: Synthesis, Structures, and Applications.
Carlos C. Romão et al.
Chemical reviews, 97(8), 3197-3246 (2002-02-20)

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