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Sigma-Aldrich

N-Ethylthiourea

99%

Synonym(s):

1-Ethylthiourea

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About This Item

Linear Formula:
C2H5NHCSNH2
CAS Number:
625-53-6
Molecular Weight:
104.17
Beilstein:
1699551
EC Number:
210-899-3
MDL number:
MFCD00004939
UNSPSC Code:
12352100
PubChem Substance ID:
24855217
NACRES:
NA.22

Assay

99%

form

solid

mp

108-110 °C (lit.)

solubility

methanol: soluble 25 mg/mL, clear, colorless

SMILES string

CCNC(N)=S

InChI

1S/C3H8N2S/c1-2-5-3(4)6/h2H2,1H3,(H3,4,5,6)

InChI key

GMEHFXXZSWDEDB-UHFFFAOYSA-N

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General description

N-Ethylthiourea forms adduct with silver halides and their single crystal X-ray structural and spectroscopic characterizations are described.

Application

N-Ethylthiourea was used in the preparation of Re (III) complexes, which are precursors for the new rhenium complexes, potentially useful in nuclear medicine. It was also used in two-step protocol for the first chemoselective cleavage of 2-hydroxy acid amides.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301

Precautionary Statements

P301 + P310 + P330

Hazard Classifications

Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Xutong Sun et al.
American journal of respiratory cell and molecular biology, 50(6), 1084-1095 (2014-01-08)
Recent studies have indicated that, during the development of pulmonary hypertension (PH), there is a switch from oxidative phosphorylation to glycolysis in the pulmonary endothelium. However, the mechanisms underlying this phenomenon have not been elucidated. Endothelin (ET)-1, an endothelial-derived vasoconstrictor
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), 39(18), 4391-4404 (2010-04-28)
Syntheses, single crystal X-ray structural and spectroscopic characterizations are described for a variety of adducts of silver halides with thiourea ('tu'), N-ethylthiourea ('ettu' = EtNH.CS.NH(2)) and N,N'-diethylthiourea ('detu' = EtNH.CS.EtNH). This study greatly extends our knowledge of the complex chemistry
Dinorah Gambino et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(14), 3085-3092 (2003-01-04)
Complexes of the type [Re(III)L6]X3, with L = thiourea, N-methylthiourea, N-ethylthiourea or N,N'-dimethytlthiourea and X = Cl- or PF6-, were prepared as suitable precursors for the synthesis of new rhenium complexes potentially useful in nuclear medicine. The infrared (IR) spectra
Erwin P Schreiner et al.
The Journal of organic chemistry, 67(24), 8299-8304 (2002-11-26)
A two-step protocol for the first chemoselective cleavage of 2-hydroxy acid amides has been developed. Mesylation of the model substrate 2-(hydroxypropionylamino)-4-methylpentanoic acid methyl ester (11) followed by treatment with N-ethylthiourea (13) allows cleavage of 2-hydroxy acid amides under smooth conditions.
M N Preobrazhenskaya et al.
The Journal of antibiotics, 44(2), 192-199 (1991-02-01)
A series of phenylthiourea and ethylthiourea derivatives of daunorubicin and its congeners was prepared by reaction of the 3'-amino group of the antibiotic with phenylisothiocyanate or ethylisothiocyanate. S-Methylation yielded S-methylisothiouromium salts which when reacted with amines resulted in an intramolecular

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