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Synthesis and reactivity of Zn-biphenyl metal-organic frameworks, introducing a diphenylphosphino functional group.

Synthesis and reactivity of Zn-biphenyl metal-organic frameworks, introducing a diphenylphosphino functional group.

Chimia (2013-08-16)

Marco Ranocchiari, Jeroen Anton van Bokhoven

摘要

Structural features, synthesis, and reactivity of Zn-biphenyl metal-organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis of a Zn-biphenyl MOF with diphenylphosphino functionalization and illustrate its structural and chemical properties.

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锌, dust, <10 μm, ≥98%

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锌, powder, <150 μm, 99.995% trace metals basis

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联苯, ≥99%

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锌, nanopowder, 40-60 nm avg. part. size, ≥99% trace metals basis

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联苯, ReagentPlus^®, 99.5%

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锌, shot, 5 mm, 99.999% trace metals basis

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联苯, PESTANAL^®, analytical standard

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