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等級
certified reference material
TraceCERT®
品質等級
產品線
TraceCERT®
儲存期限
limited shelf life, expiry date on the label
製造商／商標名
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
格式
neat
儲存溫度
2-8°C
SMILES 字串
CCCN(CC)CC1COC2(CCC(CC2)C(C)(C)C)O1
InChI
1S/C18H35NO2/c1-6-12-19(7-2)13-16-14-20-18(21-16)10-8-15(9-11-18)17(3,4)5/h15-16H,6-14H2,1-5H3
InChI 密鑰
PUYXTUJWRLOUCW-UHFFFAOYSA-N
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相关类别
一般說明
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
應用
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The spiroxamine CRM may also find the following uses:
The spiroxamine CRM may also find the following uses:
- Development of an enantioselective method to determine three fungicide residues in grapevine, sugar beet, and wheat samples by gas chromatography-tandem mass spectrometry (GC-MS/MS)
- Quantification of 19 neonicotinoids and fungicides from pollen and individual bumblebee samples using modified QuEChERS extraction with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS)
- Evaluation of a gas chromatographic method with electron capture and nitrogen phosphorus detection (GC/ECD/NPD) for the analysis of 46 pesticides in fresh peppermint samples
- Multi-residue determination of 25 pesticide residues in red wine by gas chromatography-mass spectrometry(GC-MS)
- QuEChERS extraction and liquid chromatography-tandem mass spectrometry based determination of 42 pesticides in six marijuana samples
- Investigation of three different sample preparation methods to select the most suitable one for the analysis of 98 pesticides in globe artichoke leaves and fruit samples by LC-MS and GC-MS
法律資訊
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Warning
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2
標靶器官
Eyes
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
296.6 °F
閃點（°C）
147 °C
Andrea Kunova et al.
Microorganisms, 9(7), 1541-1541 (2021-08-08)
Grapevine powdery mildew is a principal fungal disease of grapevine worldwide. Even though it usually does not cause plant death directly, heavy infections can lead to extensive yield losses, and even low levels of the disease can negatively affect the
Ignaz J Buerge et al.
Journal of agricultural and food chemistry, 64(26), 5301-5309 (2016-06-02)
Metabolism of chiral pesticides in crops is typically studied using achiral analytical methods and, consequently, the stereoisomer composition of residues is unknown. In this study, we developed an enantioselective GC-MS/MS method to quantify residues of the fungicides fenpropidin, fenpropimorph, and
Arthur David et al.
Analytical and bioanalytical chemistry, 407(26), 8151-8162 (2015-09-04)
To accurately estimate exposure of bees to pesticides, analytical methods are needed to enable quantification of nanogram/gram (ng/g) levels of contaminants in small samples of pollen or the individual insects. A modified QuEChERS extraction method coupled with ultra-high-performance liquid chromatography
Maja Pelajić et al.
Food chemistry, 200, 98-106 (2016-02-03)
A new multiresidue method was developed for determination of 25 pesticide residues in red wine by gas chromatography coupled to mass spectrometry with a single run of 23.63 min. Samples were extracted from wine with solid phase extraction using Oasis
Validation of a QuEChERS-based gas chromatographic method for multiresidue pesticide analysis in fresh peppermint including studies of matrix effects
Slowik-Borowiec M
Food Analytical Methods, 8(6), 1413-1424 (2015)
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