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Merck

424641

Sigma-Aldrich

二硫化碳

ReagentPlus®, purified by redistillation, ≥99.9%

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About This Item

经验公式(希尔记法):
CS2
CAS号:
分子量:
76.14
Beilstein:
1098293
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.21

蒸汽密度

2.67 (vs air)

品質等級

蒸汽壓力

5.83 psi

產品線

ReagentPlus®

化驗

≥99.9%

形狀

liquid

自燃溫度

212 °F

純化經由

redistillation

expl. lim.

50 %

雜質

≤0.03% (water)
≤1.5 ppm hydrogen sulfide
≤2.5 ppm sulfur dioxide
<100 ppb benzene (No single impurity > 100 ppb, measured as benzene)
<500 ppb total hydrocarbon content

顏色

APHA: ≤10

折射率

n20/D 1.627 (lit.)

bp

46 °C (lit.)

mp

−112-−111 °C (lit.)

溶解度

alcohol: miscible(lit.)
benzene: miscible(lit.)

密度

1.266 g/mL at 25 °C (lit.)

SMILES 字串

S=C=S

InChI

1S/CS2/c2-1-3

InChI 密鑰

QGJOPFRUJISHPQ-UHFFFAOYSA-N

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一般說明

Carbon disulfide is a toxic, highly volatile, flammable liquid with low ignition temperature. It can be synthesized by reacting hydrocarbon gas with sulfur. It is an important raw material for preparing viscose rayon and cellophane film. It shows fat solvent property. CS2 in water assists the peptide bond formation in amino acids.

應用

Carbon disulfide may be used in the xanthogenation of cellulose and in the synthesis of poly(ethylene trithiocarbonate).
Suitable for industrial hygiene analysis

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1

標靶器官

Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

-22.0 °F - closed cup

閃點(°C)

-30 °C - closed cup


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Luke J Leman et al.
Astrobiology, 15(9), 709-716 (2015-08-27)
Demonstrating plausible nonenzymatic polymerization mechanisms for prebiotic monomers represents a fundamental goal in prebiotic chemistry. While a great deal is now known about the potentially prebiotic synthesis of amino acids, our understanding of abiogenic polymerization processes to form polypeptides is
Copolymerization of ethylene sulfide and carbon disulfide.
Soga K, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 14(3), 677-684 (1976)
Carbon Disulfide.
Smith DE and Timmerman RW.
Kirk-Othmer Encyclopedia of Chemical Technology (2003)
Xanthogenation of lignocarbohydrates by carbon disulfide.
Efanov MV and Pershina LA.
Chemistry of Natural Compounds, 38(1), 90-94 (2002)
Margherita Maiuri et al.
Physical chemistry chemical physics : PCCP, 14(18), 6312-6319 (2012-02-15)
In carotenoids internal conversion between the allowed (S(2)) and forbidden (S(1)) excited states occurs on a sub-picosecond timescale; the involvement of an intermediate excited state(s) (S(x)) mediating the process is controversial. Here we use high time resolution (sub-20 fs) broadband

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