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等級
ACS reagent
品質等級
蒸汽密度
2.1 (vs air)
蒸汽壓力
2.7 mmHg ( 20 °C)
化驗
≥95%
形狀
liquid
自燃溫度
784 °F
expl. lim.
7.3 %, 33 °F
雜質
≤0.05% water
顏色
APHA: ≤10
折射率
n20/D 1.382 (lit.)
pH值
6.4 (20 °C, 0.01 g/L)
bp
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
適合性
clear for appearance
SMILES 字串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI 密鑰
LYGJENNIWJXYER-UHFFFAOYSA-N
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一般說明
硝基甲烷是一种脂肪族硝基化合物，通常用作化学加工和分析的溶剂。
應用
硝基甲烷可作为溶剂用于：
- FeCl3-催化的吲哚与醇傅-克烷基化反应。
- 钴催化的醛肟脱水生成腈反应。
- 醇生成羰基化合物的化学选择性氧化反应。
- 金催化的芳基取代炔烃的氢芳基化反应。
訊號詞
Warning
危險分類
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
儲存類別代碼
4.1A - Other explosive hazardous materials
水污染物質分類（WGK）
WGK 2
閃點（°F）
95.0 °F - closed cup
閃點（°C）
35 °C - closed cup
其他客户在看
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
Eagleson M.
Concise Encyclopedia Chemistry, 696-696 (1994)
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