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等级
analytical standard
质量水平
产品线
PESTANAL®
保质期
limited shelf life, expiry date on the label
技术
HPLC: suitable
gas chromatography (GC): suitable
应用
agriculture
environmental
包装形式
neat
SMILES字符串
O=C1C2=C(SC(C#N)=C(S2)C#N)C(=O)c3ccccc13
InChI
1S/C14H4N2O2S2/c15-5-9-10(6-16)20-14-12(18)8-4-2-1-3-7(8)11(17)13(14)19-9/h1-4H
InChI key
PYZSVQVRHDXQSL-UHFFFAOYSA-N
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一般描述
Dithianons belong to the quinone class of fungicides.
应用
Dithianon may be used as an analytical reference standard for the determination of dithianon in:
- Surface water samples by solid-phase extraction (SPE) and liquid chromatography coupled to quadrupole time-of-flight mass spectrometry (LC-Q-TOFMS).
- Honeybees by dispersive-SPE followed by liquid and gas chromatography coupled to tandem mass spectrometry (LC-MS/MS and GC-MS/MS) equipped with electrospray ionization (ESI) and multiple reaction monitoring (MRM) detection.
- Apples by quick, easy, cheap, effective, rugged and safe (QuEChERS) extraction as well as high performance thin-layer chromatography (HPTLC) clean-up procedures and GC-MS/MS.
- Tomatoes by QuEChERS extraction and LC coupled to triple quadrupole (QqQ) ESI-MS/MS with MRM detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
推荐产品
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
法律信息
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
P Perocco et al.
Environmental and molecular mutagenesis, 21(1), 81-86 (1993-01-01)
Cytotoxic and cell transforming activities of the pesticides cyanazine, diflubenzuron, dithianon, procymidone, and vinclozolin were investigated in vitro by utilizing the BALB/c 3T3 cell transformation test performed in the presence or in the absence of S-9 mix as an exogenous
Mikhail Y Syromyatnikov et al.
Pesticide biochemistry and physiology, 169, 104675-104675 (2020-08-24)
Bumblebees are important for crop pollination. Currently, the number of pollinators is decreasing worldwide, which is attributed mostly to the widespread use of pesticides. The aim of this work was to develop a method for assessing the genotoxicity of pesticides
M Paolini et al.
Cancer letters, 113(1-2), 221-228 (1997-02-26)
The ability of dithianon, whose mutagenic/cocarcinogenic activity has as yet not been clarified, to affect specific biomarkers of effect related to non-genotoxic cocarcinogenesis was investigated. For this purpose, several CYP-dependent reactions have been studied in liver, kidney and lung microsomes
Uwe Wanner et al.
Environmental pollution (Barking, Essex : 1987), 133(1), 35-41 (2004-08-26)
The fate of the (14)C-labelled fungicide dithianon in soil is characterized by the formation of non-extractable, "bound" residues of approximately 63% of applied amount in 64 d. Humic acids containing these "bound" residues were isolated after conducting degradation studies of
L Pozzetti et al.
Cancer letters, 141(1-2), 47-56 (1999-08-24)
With the aim of evaluating the co-carcinogenic properties of dithianon, the regio- and stereo-selective hydroxylation of testosterone was used as a multibiomarker of effect for cytochrome P450 (CYP) changes. CYP-catalysed reactions have been studied in liver, kidney and lung microsomes
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